Outline

- Waves
- Excited Particles
- Fields
- Definitions of Photons
- Types of Photons
- Gross Hydrogen Spectrum
- X-Rays
- Under Construction

## Waves

This article is about photons. But before we get to that, we have to consider some related concepts like *waves* and *fields*. So far EthnoPhysics has considered a generic particle P by objectifying some repetitive chain of events written as

Each cycle is defined by sensation. And they must be repetitive so that P can be recognized, so and so on. But we might just as well understand such a recurring sequence of sensations to be a **wave** train. That is, could represent some sort of of periodically undulating or fluctuating perception. This interpretive ambivalence is called wave-particle duality and it has been contentious during the development of physics.

However for EthnoPhysics there is no quandary; scientific facts and theories are founded on sensation, and whether we call these perceptions *particles* or *waves* is just a question of convenience. If feelings are localized, then we talk about particles. Or if sensory phenomena seem to have some extended quality, then we often use words like *wave*, *wavenumber*, *wavelength*, etc. In between, we might speak of particles that are in *excited* states. These terms are developed from a discussion of quarks as follows. Let each cycle of P be a bundle of quarks written as

And let each quark be described by its phase along with its radius vector . Then the **wavevector** of P is defined as

where is the inner radius and is the outer radius of P. Substituting-in the definitions for these radii gives the wavevector in terms of the coefficients of down quarks as

But for a perfectly free particle, and . So the wavevector of a free particle can be put plainly as

Note that is relative characteristic because the phase depends on the juxtaposition of P with some frame of reference. Let this frame be steady so that quarks do not change phase. Then if some free particles interact like then their wavevectors will combine as

This is because quarks are conserved and is defined from sums of quarks. The radius vector also relates particles and anti-particles by . So if quarks are swapped with anti-quarks, without altering the phase, then

The **average wavevector** describes some hypothetical typical quark in P using the ratios where is the total number of quarks in P.

### Inertial Frames of Reference

Let some well-known particle F be employed as a frame of reference. This just means that we use F to describe changing phenomena. Otherwise a reference frame is a compound quark like any other particle, so it can be characterized by its quark coefficients and wavevector . For example, a rigid frame of reference always has the same radius vector. Another important special case is when each component of the average wavevector of F is zero

then we say that F provides a perfectly **inertial** frame of reference. This condition is approximated when the total number of quarks is enormous. Because if the total number of quarks is huge, there will likely be some mix of quarks and anti-quarks making the terms in the radii of the numerator tend toward zero, even as the denominator gets larger.

If a frame of reference is rigid, inertial and non-rotating then we call it an **ideal** reference frame.

### Wavelengths

A **wavenumber** can be specified by the norm of a wavevector. It is written without an overline as . Then the **wavelength** of P is defined as

Thus takes a logically required, discontinuous jump when . And it leaps to zero, so perhaps we could say it *collapses*. But keep in mind that this fracture is just one of many. The wavelength is discontinuous for all values because it is defined from quark coefficients, and quark coefficients are always integers.

Sensory Interpretation: Radius vectors are defined from dynamic quarks, not baryonic quarks. So the wavevector, wavenumber and wavelength can only represent somatic and visual sensations, not thermal perceptions. And, if a frame of reference is inertial, it is big and grey.

## Excited Particles

Consider a particle P described by some repetitive chain of events written as

where each repeated cycle is a bundle of quarks

and each quark is described by its phase . Use this phase to sort quarks into a pair of sets, and , so that all quarks of the same phase are in the same set. Then and are called phase components of P, and they are out of phase with each other. We write

Some sub-set of the quarks in may be matched with quarks of the same type in . These quarks have phase symmetry with each other, so we use and to symbolize these sub-sets.

A different sub-set of quarks might be matched with *anti*-quarks of the same type. These quarks have phase anti-symmetry with each other, so we note them as and .

Some quarks in might not correspond with any quarks in and vice versa. But such lopsided possibilities seem to be superfluous so we do not consider them further.

Thus P is represented by the union of two entirely symmetric, and two purely anti-symmetric components. Quarks in the symmetric sets may vary independently of the quarks in the anti-symmetric sets. This is expressed mathematically as

where

This arrangement provides a general way of describing particles that are moved or *excited* by the absorption of additional quarks. P is defined as an **excited** particle, or said to be in an *excited-state*, if it contains at least one anti-symmetric pair of quarks

These anti-symmetric quark-pairs may be due to the absorption of a photon. Or more generally, to interactions with any field quanta.

### Ground State Particles

We say that P is in its **ground state** if it has perfect phase symmetry. Then P has no anti-symmetric quark-pairs

This definition constrains particle-models so that quark-coefficients must all be integer multiples of two when in the ground-state. It is why many nuclear particle models show patterns like 2-4-6 instead of 1-2-3. We can also evaluate the wavevector for a free particle, which is given by the sum

Since the asymmetric sets are empty, the sum is taken over just the symmetric sets, so

Thus the wavenumber of a free particle in its ground state is always zero

### The Principal Quantum Number

Whenever P interacts by absorbing or emitting a photon, its degree or *level* of excitation changes too because photons contain anti-symmetric quark-pairs. This relationship is quantified by defining the **principal quantum number** as

where is the number of ordinary down quarks in P. Note that the italic letter is employed for quark coefficients, whereas the upright font is reserved for the new quantum number. We use to describe the level of excitation, and so down-quarks retain an important role despite having almost no internal energy.

Remember that so the principal quantum number is never negative. And recall that quarks are conserved, so when P changes from some initial state , to some final state , by emitting a photon , we can write

Note that the photon’s principal quantum number can be written as

And the conservation of down-quarks implies that

Comparing the last two expressions for shows that the conservation law is always satisfied if

## Fields

A particle that is formed entirely from ethereal, imaginary and neutral components can be difficult to characterize and distinguish from other phenomena. So if there are a lot of these elusive particles in a description then it may be more convenient to group them together and refer to them collectively as a **field**. Different sorts of fields are defined by different quark distributions.

The fields that we discuss most are *electromagnetic* fields. When considered as individual particles they are called *photons*. Photons are defined from quarks that are paired with their matching anti-quarks. Different types of photons are modeled by different combinations of these pairs.

For example the gross spectrum of hydrogen is accurately described by rotating and electrochemical quark pairs. Other sorts of fields like gravity can also be modeled using these particles. Different combinations are associated with different forces. So we use them like building blocks and call them *field quanta*.

### Field Quanta

A **simple** **field quantum** is formed by a pair of quarks that are out of phase anti-particles to each other. By this definition, the net number of quarks is always zero. So these simple quanta have no mass, charge, baryon-number, lepton-number or strangeness. But they do have distinct temperatures and momenta that vary by quark-type. Here is a list of some simple field quanta.

We use the symbol to denote a simple field quantum. For any pair of quarks there are two possible arrangements that depend on their phases. That is, arrangements depend on the helicity of the reference frame as noted by or . For example consider the following pairs of negative quarks that have their phases illustrated by background shading.

Simple dynamic field quanta are little bits of momentum. They can be understood as parts or components of photons. Field quanta can move around between Newtonian particles by catching a ride on any passing photon. Momentum is conserved. So if a Newtonian particle interacts with a field quantum, then it experiences a force that is proportional to the momentum of .

A field quantum and its anti-particle have their momenta pointed in opposite directions. So if one increases, then the other decreases the total momentum of any absorbing particle. Hence, the impressed force has two possibilities; like an attraction or a repulsion, or perhaps a push vs a pull. The direction depends on phase relationships.

### Dark Quanta

In addition to the foregoing pairs, we also include and pairs as simple field quanta. This is because their internal energy is so small that any distinction between down quarks and down anti-quarks is usually ignored. Pauli’s exclusion principle is not violated because they are still distinguished by their phase.

Thus there are four quanta composed from out of phase pairs of down quarks. They all have the same temperature of -760 (K), which means that they are very stable. And they all have an internal energy that is very close to zero, about -54 *micro* electronvolts. This is utterly negligible in the realm of nuclear reactions where particle energies are typically trillions of times larger and measured in (MeV). It is also imperceptible in most atomic and chemical reactions where energies are about a million times larger. Indeed, almost the only experimental access we have to these elusive quanta comes from extremely precise observations of fine structure in atomic spectra. So by convention we almost always ignore them.

These field components are known as **dark quanta**. They are illustrated in the following images which use background shading to indicate the phase.

As individuals, these quanta rarely make any noticeable contribution to energetics. But since their internal energy is not perfectly zero, they may still be collectively relevant if there are enough of them. And enormous quantities are possible when considering astronomical distances. Then dark quanta may give rise to dark matter .

### Sub-Atomic Quanta

Atomic and molecular interactions are mediated by fields and forces too. Long-distance forces may be carried by photons. But brief, short-range forces from collisions, explosions and chemical reactions can be accurately modeled using simple field quanta. For example see the following list of forces used to describe transitions between different excited states of hydrogen.

The combination of quarks noted as in the foregoing list is called the *Lamb quantum*. It is used a lot in spectroscopic models because interacting with changes the orbital angular momentum without altering the total angular momentum. For more about these quanta, please see the discussion of fine structure in the spectrum of hydrogen.

### Strange Quanta

Simple field quanta are the building blocks of photons, but they may also be assembled into other force-carrying particles as well. For example, consider nuclear particles like the kaons. These strange particles have their rotating quarks arranged in unusual ways. So their interactions involve some different quanta too. The following strange quanta carry weak forces.

The relationship between field quanta and their forces can be developed in much more detail, but next we go back and focus on exactly what we mean by a photon.

## Definitions of Photons

Let particle P be characterized by some repetitive chain of events written as

where each repeated cycle is a bundle of quarks

and each quark is described by its phase . Use this phase to sort quarks into a pair of sets, and , so that all quarks of the same phase are in the same set. Then and are called phase components of P, and they are out of phase with each other. We write

Now let P be an almost perfectly phase anti-symmetric particle so that for all types of quarks, except perhaps down quarks. Then we define a **photon** as a particle like P, that also satisfies the conditions

These constrain the angular momentum and the inner radius so that for all photons

Notice that solitary photons are excluded from particle cores. So under some conditions, we may be able to say that is a free particle.

### Anti-Photons

For EthnoPhysics anti-photons are just like other anti-particles. So is defined from by exchanging ordinary-quarks with anti-quarks of the same type, while leaving the phase and other relationships unchanged. In a photon, for all types of quarks except down-quarks. So photons and anti-photons have just about the same characteristics as each other

But . And photons also have relative characteristics which may differ between and depending on their juxtaposition with a frame of reference. For example, the wavevector depends on the phase so that

and the two photons have symmetrically opposed wavevectors. So photons and anti-photons are mostly the same as each other, but moving in opposite directions. Next we consider some other types of photons.

## Types of Photons

Consider a photon described by an out of phase pair of components

that are almost perfectly anti-symmetric so that

for all sorts of quarks except down quarks. Many photon attributes are nil because phase anti-symmetry implies that almost every quark is matched with a corresponding anti-quark somewhere in the photon. So for most types of quark Z, the net number of quarks is zero

As for the down-quarks, is not zero. But recall that by convention, the internal energy of down-quarks is so small that it is usually taken to be zero. Then any imbalance between ordinary down quarks and down anti-quarks can be ignored. Substituting these conditions into the definitions for charge, strangeness, lepton number, baryon number and enthalpy gives

Recall that the lepton-number, baryon-number and charge are conserved, so a particle may freely absorb or emit countless photons without altering its own values for these quantum numbers. No work is required to assemble a photon because the two phase components and have radius vectors with the same norm, but opposing directions

Then too. But not all photon characteristics are null; the outer radius and the inner radius may be greater than zero. Also consider the wavevector which is found from the sum

But and are out of phase, so . And the radius vectors of particles and anti-particles are symmetrically opposed, so . These two negative factors cancel each other such that . Then we can express the wavevector as

The wavenumber is given by the norm of the wavevector, so

We can drop the subscript on because both phase components have the same norm. And recall that is the work required to build one of these phase-components. So in energetic terms, the photon’s wavenumber can be written as

Then the wavelength of a photon is

Finally recall that by definition, the inner radius is constrained such that for all photons

Photon Type | 𝜆 (m) |
---|---|

a gamma-ray | |

an X-ray | |

an ultraviolet photon | |

a visible photon | |

an infrared photon | |

a microwave | |

a radio-wave |

Then if is a free particle where and is as small as possible, the wavelength will be

Photons are classified by wavelength as noted in accompanying table. A more general treatment considers that a photon’s wavelength may also depend on its surroundings. Then the symbol is used to indicate a wavelength where any such environmental effects are negligible.

## Gross Hydrogen Spectrum

Photons that are absorbed or emitted by atomic hydrogen , are collectively known as the *spectrum* of hydrogen. They are mostly involved in the atomic and molecular interactions of everyday experience, not nuclear reactions. Energies are typically measured in (eV) rather than (MeV).

All hydrogen-spectrum photons are linked to changes in the excited states of atomic hydrogen. When goes from some initial state to some final state by emitting a photon , we write

Particles are described by their principal quantum number . This quantity is always conserved because quarks are conserved, and is directly proportional to the number of down quarks. So for any interaction, the conservation of down quarks guarantees that

Let us write and . Then, as shown earlier, quark conservation will automatically be obtained if

Here and note the photon’s coefficients for down quarks (i.e. is different from ). These relationships can be used to understand the hydrogen spectrum. Atomic interactions involving hydrogen emit many ultraviolet, visible and infrared photons. There are also some microwaves. But usually, there are no gamma-rays. We can describe photons that are not gamma-rays by first assessing their momentum as follows.

Consider finding the mechanical energy , of a photon , that is specified by a pair of phase components and written as

As discussed earlier, the wavenumber of this photon can be written as

where is the photon’s inner radius, is its outer radius and is a radius vector. The subscript on is dropped because both phase-components have the same norm. We can use this wavenumber to express the momentum of the photon, in a perfectly inertial reference frame, as

Writing-out the norm in terms of the radial components of gives

This expression can be simplified if the photon is not a gamma-ray. For long-wavelength photons the coefficients of leptonic quarks must all be zero because even one of these high energy quarks is enough to yield a gamma-ray. So the electric and magnetic radii of are null. That is, And recall that Then and so

The photon’s momentum is proportional to the absolute-value of its polar radius which is defined as

where is the enthalpy due to any chemical quarks. This expression can be simplified too because by convention . Moreover, for the high-energy up-quarks must be zero or else the photon would be a gamma-ray. Thus the polar radius is just

And the photon’s momentum can be stated as

The photon is ethereal. Its mass is zero, so

The the mechanical energy of the photon is directly proportional to its momentum and can be written as

Then substituting-in definitions for the radii gives the photon energy in terms of quark coefficients as

This formula shows the strong influence of any down-quarks on these low-energy photons. Substituting-in the relationships with discussed above gives

This expression is used to make quark-models for hydrogen by adjusting the distribution^{1}Other electrochemical quark distributions are used to model other atoms and molecular bonds. of electrochemical quarks so that

where is the Rydberg constant of hydrogen. Using this constraint to eliminate then defines the energy of a photon for the so-called *gross* structure of hydrogen spectroscopy

Measurements of photons report their wavelength which is related to the momentum by So for ethereal particles Wavelengths may also depend on a photon’s surroundings. Then the symbol is used to indicate a wavelength where any such environmental effects are negligible. We assume this is the case to write

The description of hydrogen was first put in this form by Johannes Rydberg . Models for these photons are built exclusively from electrochemical and rotating quarks.^{2}Baryonic and leptonic quarks are not used because we are not considering gamma-rays and nuclear processes. The rotating quarks all provide an angular momentum of in various ways. But the electrochemical quarks are the same for every photon because all these photons are associated with hydrogen.

Comparisons are made with experimental observations.^{3}Kramida, A., Ralchenko, Yu., Reader, J., and the NIST ASD Team (2018). NIST Atomic Spectra Database (version. 5.6.1). National Institute of Standards and Technology, Gaithersburg, MD, USA. For this reference, the lines from transitions between levels designated only by principal quantum numbers correspond to observations in which any finer structure is completely unresolved. Reported energy levels are the centre of groups of all fine-structure levels having the same . Their values are based on observations of the Sun. Some models provide very accurate descriptions that are nonetheless outside of experimental uncertainty. This is indicated with an X in the following tables.

### Lyman Series

### Balmer Series

### Paschen Series

### Brackett Series

### Other Series

In the models above, agreement with experiment is good to a few parts in a million. This would be outstanding in almost any other scientific discipline. But for atomic spectroscopy, it is mediocre. However, it *is* good enough to distinguish between competing quark-models. And so these specific quark combinations are taken to define each photon. Then later, after a discussion of atomic hydrogen, we use these models to make a more accurate description of fine structure in the hydrogen spectrum.

Calculated results depend on how quarks are distributed between phase components. For that level of detail please see the spreadsheet titled *Atoms & Photons*.

## X-Rays

The following quark-models of X-rays use only rotating and electrochemical quarks. These sorts of arrangements are called *atomic* X-ray models. It is also possible to model X-rays using leptonic quarks, but we reserve that design for the X-rays coming from nuclear-decay. Atomic X-rays are different. They are typically produced by bombarding some metallic atom , with electrons that have been accelerated to high speeds by absorbing vast quantities of photons containing electrochemical quarks. So the total number of quarks used for these models is not constrained, and rises into the thousands.

Atomic X-rays have distinct peaks in their observed energies. This phenomenon is linked to a few specific combinations of rotating quarks. Like other photons, the distribution of rotating quarks is described by the principal quantum number , and the total angular momentum quantum number , as expressed using the spectroscopic notation for X-rays. These quantities are reviewed in the table below. The wavelength of an X-ray has been established above as

where notes the work required to build , a phase component of the X-ray. The wavelength is related to the X-ray’s energy by

This relationship can be used to calculate the photon energies directly from quark-coefficients. And so here are some quark-models for the X-rays obtained by bombarding zinc, copper, iron and calcium. They are demonstrative, rather than definitive. The very close agreement with observed^{4}R.D. Deslattes, E.G. Kessler Jr., P. Indelicato, L. de Billy, E. Lindroth, J. Anton, J.S. Coursey, D.J. Schwab, C. Chang, R. Sukumar, K. Olsen, and R.A. Dragoset (2005), X-ray Transition Energies Database (version 1.2). National Institute of Standards and Technology, Gaithersburg, MD, USA. values is easy to obtain because the total number of quarks is so large. Many similar models with slightly different numbers of electrochemical quarks also fit within the limits of observation.

These X-ray models could be improved by making some additional requirement for equilibrium. Then electrochemical quark distributions could be further constrained and explained. For more detail about these calculations, please see the X-Rays spreadsheet.

## Under Construction

1 | Other electrochemical quark distributions are used to model other atoms and molecular bonds. |
---|---|

2 | Baryonic and leptonic quarks are not used because we are not considering gamma-rays and nuclear processes. |

3 | Kramida, A., Ralchenko, Yu., Reader, J., and the NIST ASD Team (2018). NIST Atomic Spectra Database (version. 5.6.1). National Institute of Standards and Technology, Gaithersburg, MD, USA. For this reference, the lines from transitions between levels designated only by principal quantum numbers correspond to observations in which any finer structure is completely unresolved. Reported energy levels are the centre of groups of all fine-structure levels having the same . Their values are based on observations of the Sun. |

4 | R.D. Deslattes, E.G. Kessler Jr., P. Indelicato, L. de Billy, E. Lindroth, J. Anton, J.S. Coursey, D.J. Schwab, C. Chang, R. Sukumar, K. Olsen, and R.A. Dragoset (2005), X-ray Transition Energies Database (version 1.2). National Institute of Standards and Technology, Gaithersburg, MD, USA. |